A knowledge of the following information from Chem 21 will be assumed for Tests
and Quizzes in Chem 21, even if it is not covered during a Chem 22 lecture.
Reactions
Numbers in parentheses are numbers in "Summary of Reactions" at the
end of each chapter. This has been updated for the 5th edition of Bruice.
Chapter 4 (Reactions of Alkenes)
- Addition of HX (1a)
- Addition of bromine, Br2(1c)
- Addition of water or alchols with an acid catalyst (1b)
- Hydroboration-oxidation (1d)
- Addition of a peroxyacid to make an epoxide (1e)
- Reduction to alkane by addition of hydrogen/Pt (or other) catalyst (2)
Chapter 6 (Reactions of Alkynes)
- Reduction to alkene and then alkane by addition of hydrogen; how to "stop"
at alkene(2)
- Reduction to trans-alkene by addition of Na in ammonia (2)
- Use of NaNH2 to remove acidic H from terminal alkyne and subsequent
use of acetylide anion as a nucleophile (3)
Chapters 8 & 9 (Reactions of Alkyl Halides)
- Nucleophilic Substitution (Chapter 8, reactions 1 & 2)
- Elimination Reactions (Chapter 9, reactions 1 & 2)
Chapter 11, (Radical Reactions)
- Radical halogenation with bromine or chlorine or NBS (N-bromosuccinimide)
(1,3,4)
- Addition of HBr in the presence of peroxides, ROOR (2)
Nomenclature
- Alkanes, alkenes, alkynes, alcohols, ethers, amines, alkyl halides and combinations
of these